The one where the Doctor is about to have his mind drained by the Great Intelligence...
A feeling of suspicion runs deep through The Web of Fear as each character has their own idea about who the traitor in their midst is. The viewer is constantly being fed red herrings by writers Mervyn Haisman and Henry Lincoln, so we're never quite sure who to not trust. Is it Evans, whose cowardice may all be a smokescreen? Is it Chorley, who has mysteriously reappeared after two episodes? Or is it Arnold, another sudden returnee?
The Doctor trusts nobody, especially the Colonel, but seems to blindly believe that Anne and Jamie couldn't possibly be the culprits. Yes, he trusts Jamie as a friend anyway, and Anne appears to be completely benign (albeit with very long claws), but how can he be sure that neither of them have been taken over by the Great Intelligence, as Professor Travers was?