The one where the Doctor leaves behind the wife he never married...
One of the many relationships threaded through these four episodes is the rivalry between Ian and Ixta, played with great relish by Ian Cullen. The episode opens with William Russell crawling terribly slowly along the tunnel he's been trapped in by Ixta, eventually to escape the other end, but the two are not done yet. When Tlotoxl leaves Ixta to guard Susan, Ian takes great pleasure in walloping his adversary from behind. However, later on, Ian still falls for the age-old trick of picking up the murder weapon and then getting found with it in his hand (exactly what happened to him in The Keys of Marinus too!).
The Doctor is reunited with Susan for the first time since The Temple of Evil, but amusingly the Doctor hasn't got time to be grateful: "My dear Susan! How glad... I'll tell you how glad I am to see you later on." Hartnell's probably ad-libbed it, but it's just so funny!